De-size or pre-treatment product for denim garment processing combined with ABS, lube and dye suspending agent. Highly sustainable products developed from natural/synthesized agro-waste. The processes can be combined with enzyme wash. One shot organic de-sizing formula performs better than the combination of chemicals in the enzymatic de-sizing process. The one-shot formula eliminates dye suspenders, modified amylase, lubrication agents, anti-back staining agents etc. In addition to cleaving the starch molecules in the alpha 1, 4 linkages, it can cleave the ring structure as well, providing smaller fragments. It also cleaves PVA sizes, formaldehyde and synthetic fixers which cannot be de-sized by enzymes. This process is considerably faster than the conventional process and saves time by combining both de-size and enzyme baths.